Electrosynthesis of Hydrogen Peroxide by Phase-Transfer Catalysis
نویسندگان
چکیده
منابع مشابه
Kinetic study of unsaturated ketones epoxidation with hydrogen peroxide through the inverse phase transfer catalysis and effect of ultrasonic waves in this epoxidation
Kinetic study of epoxidation of unsaturated ketone of mesityl oxide was studied by usingHydrogen peroxide in the presence of dodecyltrimethyl ammonium bromide (DTAB) as aninverse phase transfer catalyst. The reaction was carried out in the two-phase media of waterheptanewith 1:1 ratio in 25 °C. It was found that the order of reaction for mesityl oxide forketone concentration in the range of 0.0...
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The potential of various organic species to catalyze epoxidation of ethene by hydrogen peroxide is explored with B3LYP/6-31G* DFT calculations.
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The electrosynthesis of hydrogen peroxide using the oxygen reduction reaction has been studied in the absence and presence of power ultrasound in a non-optimized sono-electrochemical flow reactor (20 cm cathodic compartment length with 6.5 cm inner diameter) with reticulated vitreous glassy carbon electrode (30 x 40 x 10 mm, 10 ppi, 7 cm(2)cm(-3)) as the cathode. The effect of several electroch...
متن کاملkinetic study of unsaturated ketones epoxidation with hydrogen peroxide through the inverse phase transfer catalysis and effect of ultrasonic waves in this epoxidation
kinetic study of epoxidation of unsaturated ketone of mesityl oxide was studied by usinghydrogen peroxide in the presence of dodecyltrimethyl ammonium bromide (dtab) as aninverse phase transfer catalyst. the reaction was carried out in the two-phase media of waterheptanewith 1:1 ratio in 25 °c. it was found that the order of reaction for mesityl oxide forketone concentration in the range of 0.0...
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Hydrogen peroxide can be electrosynthesized from oxygen in [bmim][BF(4)]-water and used in situ for the epoxidation of alkenes.
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ژورنال
عنوان ژورنال: Joule
سال: 2019
ISSN: 2542-4351
DOI: 10.1016/j.joule.2019.09.019